coke deposited on catalyst

Characterization of coke deposited from cracking of ...

T1 - Characterization of coke deposited from cracking of benzene over USY zeolite catalyst. AU - Radwan, Aly Moustafa. AU - Kyotani, Takashi. AU - Tomita, Akira. PY - 2000/2/4. Y1 - 2000/2/4. N2 - Catalytic cracking of benzene was carried out under He or H2 gas flow at 1.0 and 5.0MPa in the temperature range of 500-800°C.

The chemistry of coke deposits formed on a Pt Sn catalyst ...

Structure of the insoluble coke Although a chemical analysis of this coke was not possible, a qualitative analysis of the coke deposited on the catalyst before and after extraction of soluble coke (Fig. 5) was made by IR. As shown, the bands for aromatic structures (notably at 1610 cm- 1) 4000 3ooo 2000 ~5oo ~ooo Wovenurnber ( cm'll sSo Fig. 5.

Coke resistance of Ni-based catalysts enhanced by cold ...

However, the stability of Ni-based catalysts is unsatisfactory due to severe coke formation and sintering of active metal at the high temperature, resulting in deactivation of carbon deposits on the catalyst surface [16,,,, ].

Catalytic Cracking Process, Fouling, and Cleaning Methods

The coke will coat the catalyst preventing it from promoting the cracking reaction. The catalyst is renewed by burning off the coke deposits from the catalyst surface during regeneration. The cracked hydrocarbons are separated using conventional fractionating equipment.

US20070261714A1 - In-situ continuous coke deposit removal ...

A coke removal system removes coke deposits from the walls of a high temperature passage in which hydrocarbon fuel is present. The system includes a carbon-steam gasification catalyst and a water source. The carbon-steam gasification catalyst is applied to the walls of the high temperature passage. The water reacts with the coke deposits on the walls of the high temperature passage to remove ...

Dynamics of carbon formation during the catalytic ...

The formation, growth and transformation of the carbon residue (coke) deposited on the catalyst during the raw bio-oil hydrodeoxygenation have been studied. These deposits have a great impact on the overall process performance, and they have been formed in accelerated deactivation conditions (450 °C, 65 bar, space time of 0.09 g h g bio ...

COKE FORMATION ON SILICA-ALUMINA CRACKING CATALYSTS

The mechanism of coke formation on silica-alumina cracking catalysts was studied by analysis of cracking experiments with seven pure hydrocarbons at 445' C. and n-hexadecane at 500" C. under a variety of process conditions. Coke deposits were isolated from selected catalyst samples for infrared spectral examination.

Temperature-Programmed Oxidation of Coke Deposited on ...

Coke deposited on catalytic cracking catalysts has been investigated by continuously monitoring evolved CO and CO2 during temperature-programmed oxidation (TPO) in a 1% O2/N2 mixture. Analyses were carried out on spent samples recovered from an industrial catalytic cracker and on coke prepared in the laboratory by exposure of fresh catalyst to 1-hexene and cyclohexene at 500 …

Temperature Programmed Oxidation Coupled with In Situ ...

The characterization of coke deposited on a Ni/La 2 O 3-αAl 2 O 3 catalyst used in the steam reforming of bio-oil has been studied by temperature programmed oxidation (TPO) coupled with different in situ techniques: thermogravimetry (TG), modulated thermogravimetry (MTG), FTIR spectroscopy with mass spectrometry (MS), Raman spectroscopy, and differential scanning …

Temperature-Programmed Oxidation of Coke Deposited by 1 ...

The properties of coke deposited by 1-octene on fresh cracking catalysts have been investigated by analyzing CO, CO 2, and H 2 O evolution during temperature-programmed oxidation (TPO). Of particular significance in the analysis is that the combustion mechanism dependence of the CO and CO 2 profiles were taken into account. Catalysts were laboratory coked at temperatures ranging …

(PDF) Effect of Coke Deposition on the Effective ...

Schulz et al [11] concluded that the coke deposit inside zeolite pores consist two ring aromatic, meanwhile Karge et al [12] reported two kind of coke on zeolite catalyst first at low temperature ...

Structural characterization of coke deposits on industrial ...

In order to counteract the effects of coke deposition, it is vital to know the location as well as the nature and composition coke deposited on the spent catalysts. In the present study, spent Pt-Sn/Al 2O 3 catalysts used in the industrial reactors for selective dehydrogenation of C 10–C 13 n-paraffins to mono-olefins at different coke ...

Solved: Burning The Coke Deposited On The Catalyst Particl ...

Question: Burning The Coke Deposited On The Catalyst Particles Generates All The Heat Necessary For Catalytic Cracking. Therefore, The Coke Burning Rate Is A Critical Parameter To Control The Rate Of Cracking. The Composition Of Dry Flue Gas From The Regenerator Of An FCC Unit Is Given In Vol% As Follows: Gas Volume % N2 81.6 CO2 15.7 CO 1.5 O2 1.2 The Dry Air ...

Coke deposits on Pt/Al2O3 catalysts of varying ...

Coke deposition during cyclopentane reaction was investigated on Pt/Al2O3 catalysts of varying dispersity. For all working pressures the higher the metallic accessibility, the higher the amount of coke deposited on the catalyst. Nevertheless, coke deposited on the less dispersed catalysts is more toxic for the metallic function. An increasing metal accessibility improves the graphitization of ...

Temperature-Programmed Oxidation of Coke Deposited on ...

Coke deposited on catalytic cracking catalysts has been investigated by continuously monitoring evolved CO and CO 2 during temperature-programmed oxidation (TPO) in a 1% O 2 /N 2 mixture. Analyses were carried out on spent samples recovered from an industrial catalytic cracker and on coke prepared in the laboratory by exposure of fresh catalyst to 1-hexene and cyclohexene at 500 …

Study of coke deposited on atmospheric-residue ...

The influence of the catalyst loading, pressure, and temperature on the formation of different forms of carbonaceous deposits during the atmospheric-residu Study of coke deposited on atmospheric-residue hydrocracking catalysts | SpringerLink

Coke Aging and Its Incidence on Catalyst Regeneration ...

The effects of a sweeping treatment on the activity recovery, coke content, H/C ratio, and kinetics of coke combustion have been studied in the coke deposited on an HZSM-5 zeolite. The reaction test studied is the transformation of acetone into hydrocarbons at 400 °C, and the gases used in the sweeping are He, H2, and steam. Aside from the partial elimination of coke, which occurs with all ...

Causes of FCC reactor coke deposits identified (Journal ...

@article{osti_5172136, title = {Causes of FCC reactor coke deposits identified}, author = {McPherson, L J}, abstractNote = {Several years ago, ARCO personnel described four distinct types of coke produced in the catalytic cracking process. This coke is deposited on the catalyst during the reaction stage and is subsequently burned off in the regenerator to provide the essential heat to maintain ...

Microstructural Investigation of Coke Deposition in ...

The coke content of the catalyst after 4 h experiment was 24 wt% of the deposits comprising residual oil, asphaltene, metals and coke was determined using thermogravimetric analyser, and the details had been reported elsewhere [7, 8]. The focus of this study is on the impact of coke deposition on the pore network structure of the catalyst pellet.

Discerning the Location and Nature of Coke Deposition from ...

The formation of carbonaceous deposits (coke) in zeolite pores during catalysis leads to temporary deactivation of catalyst, necessitating regeneration steps, affecting throughput, and …

Characterization of coke deposited on Pt/alumina catalyst ...

The TPO of carbon deposited on the 0.61% Pt/alumina catalyst during ATR, POX, and SR of tetradecane is shown in Fig. 1.Although the CO 2 peaks differ in magnitude, each reaction produced three peaks at about ∼100, 420, and 550 °C. Low temperature coke (<200 °C) formation is the result of condensation and rearrangement steps and its composition depends on the reactant, …

Chemical Origin of Coke Deposited on Catalyst Surface ...

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Coke and Product Profiles Formed Along the Catalyst Bed ...

The addition of Re to a Pt catalyst has a similar effect on the coke profile and on the C5 naphthene profile of the Pt catalyst as increasing its operation pressure, i.e., shifting the maximum of coke and C5 naphthene profile from bed outlet to inlet. Additionally, pressure at which coke is deposited …

Study of X-ray photoelectron spectroscopy on coke ...

The coke deposited on the surfaces of Ni/HZSM-5 catalyst in bio-oil hydrodeoxygenation (HDO) was characterized by using a technique of X-ray photoelectron spectroscopy. The results show that the compounds with carbon related oxygen are the main constituent of the coke on the Ni/HZSM-5 catalysts. The amount of carbon compounds with two oxygen atoms is decreased with …

Material Balance for FCC Regenerator Problem Burning the coke

Material Balance for FCC Regenerator Problem Burning the coke. deposited on the catalyst particles generates all the heat necessary for catalytic cracking. Therefore, the coke burning rate is a critical parameter to control the rate of cracking. The composition of dry flue gas from the regenerator of an FCC unit is given in vol% as follows: Gas ...

US4450241A - Endothermic removal of coke deposited on ...

US4450241A US06/418,880 US41888082A US4450241A US 4450241 A US4450241 A US 4450241A US 41888082 A US41888082 A US 41888082A US 4450241 A US4450241 A …

Regeneration of coked catalysts: The effect of aging upon ...

Regeneration of coked catalysts: The effect of aging upon the characteristics of the coke deposits

Material Balance for FCC Regenerator | Chegg.com

Burning the coke deposited on the catalyst particles generates all the heat necessary for catalytic cracking. Therefore, the coke burning rate is a critical parameter to control the rate of cracking. The composition of dry flue gas from the regenerator of an FCC unit is given in vol% as follows: Gas Volume % N2 81.6. CO2 15.7. CO 1.5. O2 1.2

Structure and composition of hard coke deposited on ...

The second region is attributed to the reaction of hard coke-aromatic compounds and coke deposited in the deep pores of the catalyst 28, generating CO, NO and CO 2 at an elevated temperature ...

Fluid Catalytic Cracking (FCC) | FSC 432: Petroleum Refining

A carbon-rich byproduct of catalytic cracking, termed "coke," deposits on catalyst surfaces and blocks the active sites. FCC is considered a carbon rejection process because the coke deposited on the catalyst surface and eventually burned off for heat is rich in carbon and thus enables the production of large quantities of a light ...